Particle analyses and laboratory experiments reveal how ultrafine particles form – Study by Goethe University Frankfurt in collaboration with the Hessian Agency for Nature Conservation, Environment and Geology
Measurements conducted by the Hessian Agency for Nature Conservation, Environment and Geology (HLNUG) in recent years have shown that Frankfurt International Airport is a major source of ultrafine particles and that these can disperse over long distances across the city. In collaboration with experts at the HLNUG, researchers at Goethe University Frankfurt have now discovered that the ultrafine particles partly consist of synthetic jet oils. The research team has deduced that emissions from lubrication oils must be lowered in addition to those from kerosene in order to reduce the concentration of ultrafine particles and thus improve air quality.
FRANKFURT. Ultrafine particles form during combustion processes, for example when wood or biomass is burned, as well as in power and industrial plants. Alongside road traffic, large airports are a major source of these ultrafine particles, which are less than 100 millionths of a millimetre (100 nanometres) in size. Because they are so small, they can penetrate deep into the lower respiratory tract, overcome the air-blood barrier and, depending on their composition, cause inflammatory reactions in the tissue, for example. What's more, ultrafine particles are suspected of being capable of triggering cardiovascular diseases.
Since several years, the Hessian Agency for Nature Conservation, Environment and Geology (HLNUG) has been measuring the number and size of ultrafine particles at various air monitoring stations in the vicinity of Frankfurt International Airport, for example in the Frankfurt suburb of Schwanheim and in Raunheim. Last year, scientists led by Professor Alexander Vogel at Goethe University Frankfurt analysed the chemical composition of the ultrafine particles and came across a group of organic compounds which, according to their chemical fingerprints, originated from aircraft lubrication oils.
The research team has now corroborated this finding by means of further chemical measurements of the ultrafine particles: the particles originated to a significant degree from synthetic jet oils and were particularly prevalent in the smallest particle classes, i.e. particles 10 to 18 nanometres in size. Such lubrication oils can enter the exhaust plume of an aircraft's engines, for example through vents where nanometre-sized oil droplets and gaseous oil vapours are not fully retained.
In laboratory experiments, the researchers also succeeded in reproducing the formation of ultrafine particles from lubrication oils. To this end, a common engine lubrication oil was first evaporated at around 300 °C in a hot gas stream, which simulated the exhaust plume of an aircraft engine, and subsequently cooled down. The number-size distribution of the freshly formed particles was then measured.
Alexander Vogel, Professor for Atmospheric Environmental Analytics at the Institute for Atmospheric and Environmental Sciences of Goethe University Frankfurt, explains: “When the oil vapour cools down, the gaseous synthetic esters are supersaturated and form the nuclei for new particles that can then grow fast to around 10 nanometres in size. These particles, as our experiments indicate, constitute a large fraction of the ultrafine particles produced by aircraft engines. The previous assumption that ultrafine particles originate primarily from sulphur and aromatic compounds in kerosene is evidently incomplete. According to our findings, lowering lubrication oil emissions from jet engines holds significant potential for reducing ultrafine particles."
The experiments show that the formation of ultrafine particles in jet engines is not confined to the combustion of kerosene alone. Potential mitigation measures should take this into consideration. This means that using low-sulphur kerosene or switching to sustainable aviation fuel cannot eliminate all the pollution caused by ultrafine particles.
A comprehensive scientific study by the Federal State of Hesse, which will start in 2023, will examine pollution from ultrafine particles and their impact on health. In this context, the results from the current study can help to identify airport-specific particles and derive possible mitigation measures.
Florian Ungeheuer, Lucía Caudillo, Florian Ditas, Mario Simon, Dominik van Pinxteren, Dogushan Kilic, Diana Rose, Stefan Jacobi, Andreas Kürten, Joachim Curtius, Alexander L. Vogel: Nucleation of jet engine oil vapours is a large source of aviation-related ultrafine particles. Communications Earth & Environment (2022)
Caption: Lubrication oil in the hot exhaust plume of an aircraft engine can form ultrafine particles as soon as the plume cools down. This has now been corroborated in a study by Goethe University Frankfurt and the Hessian Agency for Nature Conservation, Environment and Geology.
Photo: Alexander Vogel, Goethe University Frankfurt
Professor Alexander L. Vogel
Institute for Atmospheric and Environmental Sciences
Goethe University Frankfurt
Tel. +49 (0)69 798-40225
Twitter: @al_vogel, @HLNUG_Hessen
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